Swallowing will cause burns to the mouth and throat, gastrointestinal irritation, and may be fatal. If patient is not breathing, start artificial respiration, preferably with a demandvalve resuscitator, bagvalvemask. Chemtrec 8004249300 outside usa 7035273887 1216 6th ave n. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Hydrazine is highly toxic and dangerously unstable unless handled in solution as e. The raschig process, the original commercial production process for hydrazine, involves oxidation of ammonia to chloramine. Ac411745000, ac611195000, bp1200100, o3106500 synonyms. Lanxess hydrazine hydrate is primarily used as an intermediate. Hydrazine dihydrochloride material safety data sheet cas. Hydrazine sulphate cas no 10034932 material safety data sheet sds msds.
Sigmaaldrich 3050 spruce street saint louis mo 63103 usa telephone. Hydrazine hydrate, 80% hydrazine, 51% revision date 11jul2019 nfpa 6. As a waterbased solution, hydrazine hydrate and its derivatives are supplied by arkema to be widely used as reducing agent, blowing agent, corrosion inhibitor, oxygen scavenger or intermediate of synthesis. Hydrazine included in the candidate list of substances of very high concern svhc according to regulation ec no. However all contact with oxidizing products, mineral or organic, should be avoided. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Hydrazine is the simplest diamine mainly used as a reducing agent. Nevertheless, the properties of hydrazine have been evaluated as far as possible. Transportation information this product is a regulated material for domestic ground transporation, per cfr title 49.
It is a simple pnictogen hydride, and is a colorless and flammable liquid with an ammonialike odor. Willstatterstrasse 11 poison information center main. Sensitive determination of hydrazine with detection limit of 10. Hydrazine is highly explosive in the presence of oxidizing materials and metals and incompatible with moisture and acids msds 2005. According to reach regulation annex xiii, the pbtvbvp assessment does not apply to inorganic chemicals. First aid measures general advice consult a physician. Most important symptomseffects, acute and delayed immediate first aid ensure that adequate decontamination has been carried out. The measurement of hydrazine requires a high ph of the sample.
Anhydrous hydrazine ah monomethyl hydrazine mmh uns dimethyl hydrazine udmh hydrogen peroxideh 2 o 2 dinitrogen tetroxiden 2 o 4 hydroxylterminated polybutadienehtpb ammonium perchlorate ap e thylamine 1anhydrous hydrazine. Harmful by inhalation, contact with skin and if swallowed. Cover with dry earth, sand or other noncombustible material followed by a plastic sheet to. Cleartech will send any available supplementary handling, health, and safety information to you at your request. The diisopropylamine is dissolved in the water while flowing through a diffusion tube. Show this safety data sheet to the doctor in attendance. Other organs that may be affected include the kidneys, lungs, blood system and central nervous system.
Hydrazine hydrate 302012 mainly for water and effluent 243555% treatments hydrazine hydrate 302012 mainly for synthesis 608085100% and derivatives manufacturing liozan 302012 activated hydrazine hydrate for boiler water treatment hydrazine derivatives hydrazine salts dihydrazine sulphate 55% 464807 synthesis intermediate, denox. Hydrazine hydrate, 80% hydrazine, 51% revision date 11jul2019 4. Hydrazine undergoes dehydrogenation in the presence of bimetallic nirh nanoparticles nps supported on nitrogendoped porous carbon npc derived from metalorganic frameworks zif8 to afford hydrogen. Identification of the substancepreparation and of the companyundertaking product name.
The hydrate may be produced commercially by three methods. Hydrazine sulfate is soluble in water but practically insoluble in ethanol. Dermal contact may result in irritation or severe burns. With locations across canada, cleartech delivers quality chemicals and equipment from the top suppliers that you know and trust with the technical advice you need. Pyridine acs safety data sheet according to the federal final rule of hazard communication revised on 2012 hazcom 2012 jubilant life sciences limited page 1 of 10. After neutralization, transfer material to appropriate dot container for proper disposal. These solutions must be stored away from direct sunlight, in a cool warehouse. Cas number, unna number, dot hazard label, uscg chris code. The extent of acetylation decreased, the hydrazine. Methylhydrazine fires produce irritating nitrogen oxides. Acute shortterm inhalation exposure to high levels of methylhydrazine may cause lacrimation, eye redness, nasal and respiratory irritation, headache, malaise, vomiting, diarrhea, ataxia, anoxia, cyanosis, tremors, and convulsions in humans.
Hydrazine 64% material safety data sheet msds catalog. Read the product manufacturers material safety data. Fisher scientific 1 reagent lane fair lawn, nj 07410 for information, call. Methylhydrazine is used as a highenergy fuel in military applications.
Our product found applications in various industrial sectors such as water treatment, polymerization, agrochemicals, and pharmaceuticals. Symptoms of acute shortterm exposure to high levels of hydrazine may include irritation of the eyes, nose, and throat, dizziness, headache, nausea, pulmonary edema, seizures, and coma in humans. Hydrazine is also flammable in the presence of open flames, sparks, heat, and oxidizing materials msds 2005. Aqueous hydrazine solution diamide hydrate cas number. Hydrazine is an inorganic compound with the chemical formula n 2 h 4. The liver is thought to be the primary target organ in hydrazine exposure. Pyridine acs safety data sheet according to the federal final. Dilute hydrazine hydrate with water so the concentration of hydrazine is less than 5% ww.
Hydrazine concentration considered to be immediately dangerous to life and health is 80 ppm. Hydrazine hydrate 80% extra pure msds cas 10217524 msds. Unlike concentrated solutions of hydrazine hydrate, the 24, 35, and 55 % solutions are not inflammable. This material does not contain any hazardous air pollutants. Add an equal volume of 5% calcium hypochlorite aqueous solution.
Cleartech is a canadian leader in the distribution of chemicals and chemical equipment for municipal, commercial and industrial uses. The maximum allowable concentration of hydrazine tlv. Water spray, dry chemical, alcohol foam, or carbon dioxide. Hydrazine vapor in air is flammable at and above 4. If you have any questions or concerns please call our customer service or technical service department. Chemtrec 8004249300 outside usa 7035273887 1216 6th ave n kent wa 98032 phone. Property hydrazine hydrazine sulfate molecular weight 32. Hydrazine hydrate, 55% hydrazine, 35% revision date 11jul2019 4. Hydrazine sulphate material safety data sheet cas no 10034. Above the flash point, explosive vaporair mixtures may be formed. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Nioshtic2 search results for hydrazinesnioshtic2 is a searchable database of worker safety and health publications, documents, grant reports, and journal articles supported in whole or in part by niosh.
The sample enters at the sample inlet, passes the filter and the needle valve, where sample flow is adjusted and flows. As hydrazine is purely inorganic, it cannot be degraded in sewage treatment plants. Persons with preexisting skin disorders or eye problems, or impaired liver, kidney or. Chemical product and company identification product name. Hydrazine 302012 hazard summary individuals may be exposed to hydrazine in the workplace or to small amounts in tobacco smoke. Hydrazine hydrate is a clear and colorless liquid at ambient temperatures, with a pungent, ammonialike fishy odor. Hydrazine anhydrous,monomethyl hydrazinemmh,unsdimethyl. Hydrazine and hydrazine sulfate national toxicology program. Identification of the substancemixture and of the companyundertaking. Corrosive r34 causes burns classification r202122 harmful by inhalation, contact with skin and if swallowed.
Pdf, xml, xfo and any other electronic files rendered by an infosafe system for infosafe msds. The raschig process, the original commercial production process for hydrazine. Hydrazine is used in agricultural chemicals pesticides, chemical blowing agents, pharmaceutical intermediates, photography chemicals, boiler water treatment for corrosion protection, textile dyes, and as fuel for rockets and spacecraft. H065053, h065071, h070048, h070050, h070071 synonyms. Neutralize spilled hydrazine by diluting with water to a 5% or less solution. Hydrazine sulfate ld50 oral, rat 601 mgkg hydrazine sulfate is listed by the ntp as anticipated human carcinogen. In the case of contact with eyes, rinse immediately with plenty of water and seek medical. Identification of the substancemixture and of the companyundertaking 1. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Hydrazine is toxic to the liver, ruptures red blood cells, and may cause kidney damage.
Physical and chemical properties of hydrazine and hydrazine sulfate are listed in the following table. Safety data sheet northwest missouri state university. Firstaid measures general advice show this safety data sheet to the doctor in attendance. Accidental release measures personal precautions ensure adequate ventilation. Hydrazine can be used in nickel plating, the removal of halogens from wastewaters, as an.
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